Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Crystal, defect, point mesophase,

The study of defects in liquid crystal systems is rooted in the understanding of defects in the solid state. For instance, crystals are rarely perfect and usually contain a variety of defects, e.g., point defects, line defects, or dislocations, and planar defects such as grain boundaries. In addition to these typical imperfections of the solid state, liquid crystals can also exhibit defects known as disclinations. These defects are not usually found in solids and result from the fact that mesophases have liquid-like structures that can give rise to continuous but sharp changes in the orientations of the molecules, i.e., sharp changes in orientation occur in the director field. [Pg.3099]

Between crossed polars these defects appear as dark lines or brushes with curved or irregular shapes that correspond to extinction positions of the director and molecular long axes. Thus, the director can be either parallel or perpendicular to the polarizer and analyzer. The brushes tend to cover the specimen in rather a continuous way, indicating the liquid-like nature of the mesophase. The points where the brushes meet are called singularities in the texture (see Figure 3A). For nematic phases two forms of schlieren defect are found, one where two brushes meet at a point and one where four brushes meet. All tilted smectic phases (C, I, F, and ferrielectric C), except for the antiferroelectric phase, exhibit four brush singularities. Therefore, this provides a simple way of distinguishing between smectic and nematic phases. It should be noted that phases such as smectics A and B(hexatic) and crystal phases B(crystal), E, G, H, J, and K do not exhibit schlieren textures and so this narrows down the possibilities for phase identification. [Pg.3102]


See other pages where Crystal, defect, point mesophase, is mentioned: [Pg.50]    [Pg.320]    [Pg.87]    [Pg.2]    [Pg.146]    [Pg.3098]    [Pg.2789]    [Pg.354]    [Pg.361]    [Pg.462]    [Pg.2149]   


SEARCH



Crystal defects

Crystal-mesophase

Crystallization mesophases

Crystallization points

Crystals point defects

Defect point

Mesophase

Mesophase crystallization

Mesophases

Mesophases defects

© 2024 chempedia.info