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Crotyl alcohols

Recovery of the wopropyl alcohol. It is not usually economical to recover the isopropyl alcohol because of its lo v cost. However, if the alcohol is to be recovered, great care must be exercised particularly if it has been allowed to stand for several days peroxides are readily formed in the impure acetone - isopropyl alcohol mixtures. Test first for peroxides by adding 0-6 ml. of the isopropyl alcohol to 1 ml. of 10 per cent, potassium iodide solution acidified with 0-6 ml. of dilute (1 5) hydrochloric acid and mixed with a few drops of starch solution if a blue (or blue-black) coloration appears in one minute, the test is positive. One convenient method of removing the peroxides is to reflux each one litre of recovered isopropyl alcohol with 10-15 g. of solid stannous chloride for half an hour. Test for peroxides with a portion of the cooled solution if iodine is liberated, add further 5 g. portions of stannous chloride followed by refluxing for half-hour periods until the test is negative. Then add about 200 g. of quicklime, reflux for 4 hours, and distil (Fig. II, 47, 2) discard the first portion of the distillate until the test for acetone is negative (Crotyl Alcohol, Note 1). Peroxides generally redevelop in tliis purified isopropyl alcohol in several days. [Pg.886]

Some alcohols that have been converted into the corresponding fluorides by reactions with diethyldminosulfur trifluoride include 1-octanol, 2-methyl-2-butanol, isobutyl alcohol, cyclooctanol, ethylene glycol, crotyl alcohol, 2-phenylethanol, 2-bromoethanol, ethyl lactate, and ethyl a-hydrox3maphthaleneacetate. ... [Pg.73]

Allyiic rearrangements are observed m the reactions of allylic alcohols with dialkylaminosulfur trifluorides [95 130] Both crotyl alcohol and buten 3 ol give... [Pg.229]

Cleavage of the methallyl ester is achieved in 80-95% yield by solvolysis in refluxing 90% formic acid. Cinnamyl and crotyl alcohols are similarly cleaved. ... [Pg.411]

As an example of the system in which parallel and consecutive reactions occur simultaneously, we have chosen the hydrogenation of crotonaldehyde, which may lead through two two-stage paths (via butyraldehyde and via crotyl alcohol) to the same final product, butanol... [Pg.43]

Fig. 9. Dependence of relative molar concentrations Wj/nA0 of reaction components on reciprocal space velocity W/F (hr kg mole 1) in the parallel-consecutive hydrogenation of crotonaldehyde. Temperature 160°C, catalyst Pt-Fe/Si02 (1% wt. Pt, 0.7% Fe), initial molar ratio of reactants G = 10. The curves were calculated (1—crotonaldehyde, 2—butyraldehyde, 3—crotyl alcohol, 4—butanol) the points are experimental values. Fig. 9. Dependence of relative molar concentrations Wj/nA0 of reaction components on reciprocal space velocity W/F (hr kg mole 1) in the parallel-consecutive hydrogenation of crotonaldehyde. Temperature 160°C, catalyst Pt-Fe/Si02 (1% wt. Pt, 0.7% Fe), initial molar ratio of reactants G = 10. The curves were calculated (1—crotonaldehyde, 2—butyraldehyde, 3—crotyl alcohol, 4—butanol) the points are experimental values.
From the results of this kinetic study and from the values of the adsorption coefficients listed in Table IX, it can be judged that both reactions of crotonaldehyde as well as the reaction of butyraldehyde proceed on identical sites of the catalytic surface. The hydrogenation of crotyl alcohol and its isomerization, which follow different kinetics, most likely proceed on other sites of the surface. From the form of the integral experimental dependences in Fig. 9 it may be assumed, for similar reasons as in the hy-drodemethylation of xylenes (p. 31) or in the hydrogenation of phenol, that the adsorption or desorption of the reaction components are most likely faster processes than surface reactions. [Pg.45]

It is noteworthy that even a separate treatment of the initial data on branched reactions (1) and (2) (hydrogenation of crotonaldehyde to butyr-aldehyde and to crotyl alcohol) results in practically the same values of the adsorption coefficient of crotonaldehyde (17 and 19 atm-1)- This indicates that the adsorbed form of crotonaldehyde is the same in both reactions. From the kinetic viewpoint it means that the ratio of the initial rates of both branched reactions of crotonaldehyde is constant, as follows from Eq. (31) simplified for the initial rate, and that the selectivity of the formation of butyraldehyde and crotyl alcohol is therefore independent of the initial partial pressure of crotonaldehyde. This may be the consequence of a very similar chemical nature of both reaction branches. [Pg.46]

From the study of the influencing of single reactions by products and by other added substances and from the analysis of mutual influencing of reactions in coupled systems, the following conclusions can be drawn concerning adsorption of the reaction components. (1) With the exception of crotyl alcohol on the platinum-iron-silica gel catalyst, all the substances present in the coupled system, i.e. reactants, intermediate products, and final products, always adsorbed on the same sites of the catalytic surface (competitive adsorption). This nonspecificity was established also in our other studies (see Section IV.F.2) and was stated also by, for example, Smith and Prater (32), (2) The adsorption of starting reactants and the desorption of the intermediate and final products appeared in our studies always as faster, relative to the rate of chemical transformations of adsorbed substances on the surface of the catalyst. [Pg.49]

Ki adsorption coefficient in the monomolecular isomerization of crotyl alcohol... [Pg.50]

Between these two extremes of spontaneous rearrangement and total failure to rearrange, Braverman and Stabinsky36-38 have observed intermediate behavior. The reaction of crotyl alcohol with C13CSC1 afforded an equilibrium mixture of both crotyl trichlormethanesulfenate (13) and a-methylallyl trichloromethyl sulfoxide (14, equation 9). [Pg.722]

The allylation of carbonyl compounds in aqueous media with SnCl2 can also employ allylic alcohols (Eq. 8.39)84 or carboxylates85 in the presence of a palladium catalyst. The diastereoselectivity of the reactions with substituted crotyl alcohols was solvent dependent. Improved diastereoselectivity was obtained when a mixture of water and THF or DMSO was used, instead of the organic solvent alone. [Pg.231]

Crotononitrile, b482 trans-Crotonyl alcohol, c311 Crotyl alcohols, b486, b487 Crotyl bromide, b276 Crotyl chloride, c79... [Pg.155]

The reaction which is carried out in presence of isopropyl alcohol is also called Meerwein-Pondorf-Verley reduction. An example is the reduction of crotonaldehyde to crotyl alcohol. [Pg.296]

J. E. Bailie, and G. J. Hutchings, Promotion by sulfur of gold catalysts for crotyl alcohol formation from crytonaldehyde hydrogenation, Chem. Commun. 21, 2151-2152 (1999). [Pg.52]

C. Crotyl diazoacetate. A solution of 10.0 g. (0.038 mole) of the />-toluenesulfonylhydrazone of glyoxylic acid chloride in 100 ml. of methylene chloride is cooled in an ice bath. Crotyl alcohol (2.80 g. or 0.038 mole) (Note 7) is added to this cold solution, and then a solution of 7.80 g. (0.077 mole) of redistilled triethyl-amine (b.p. 88.5-90.5°) in 25 ml. of methylene chloride is added to the cold reaction mixture dropwise and with stirring over a 20-minute period. During the addition a yellow color develops in the reaction mixture and some solid separates near the end of the addition period. The resulting mixture is stirred at 0° for 1 hour and then the solvent is removed at 25° under reduced pressure with a rotary evaporator. A solution of the residual dark orange liquid in approximately 200 ml. of benzene is thoroughly mixed with 100 g. of Florisil (Note 8) and then filtered. The residual Florisil, which has adsorbed the bulk of the dark colored by-products, is washed with two or three additional portions of benzene of such size that the total volume of the combined benzene filtrates is 400-500 ml. This yellow benzene solution of the diazoester is concentrated under reduced pressure at 25° with a rotary evaporator, and the residual yellow liquid is distilled under reduced pressure. (Caution This distillation should be conducted in a hood behind a safety shield) (Note 9). The diazo ester is collected as 2.20-2.94 g. (42-55%) of yellow liquid, b.p. 30-33° (0.15 mm.), n T) 1.4853 - 1.4856 (Note 10). [Pg.13]

Glyoxylic acid chloride />-toluene-suUonylhydrazone, 49, 23 reaction with crotyl alcohol, 49, 24 Glyoxylic acid, condensation with p-toluenesulfonylhydrazide, 49, 22 Glyoxylic acid, />-toluenesulfonylhydra-zone, 49, 22... [Pg.72]


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Crotyl

Crotyl alcohol, from crotonaldehyde

Crotyl alcohol, oxidation

Crotylation

Of crotyl alcohol

Physical Properties of Crotyl Alcohol

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