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Corresponding states entropy change from

The maximum term corresponds to the equilibrium distribution in which =JV- = We have thus calculated directly the entropy corresponding to the equilibrium distribution. To show how the entropy production accompanying the change from some initial distribution to the equilibrium state can be expressed in the form (3.21), we introduce the extent of change to measure the number of molecules which have passed from one compartment to the other. If, initially, there are and JV molecules in the two compartments, then at any instant... [Pg.46]

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See also in sourсe #XX -- [ Pg.247 ]



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