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Star-shaped copolymers core-first method

Synthesis of star-shaped copolymers by the core-first method. 868... [Pg.824]

Two general strategies are possible for the synthesis of star-shaped copolymers The arm-first method is based on the reaction of living chains with plurifunctional electrophiles carrying at least three reacting groups alternatively, polymerization can be initiated by a multifunctional initiator according to the core-first method. [Pg.865]

PEG-based star copolymers bearing cationic cores were prepared by Cho et al. using the arm-first ATRP method (Scheme 3.7). ° The PEG-based macromonomer was polymerized with DMAEMA in the presence of a degradable crosslinker to obtain well-defined star-shaped nanoparticles of 120 kDa with degradable and cationic cores. The PEG-based star-shaped... [Pg.70]

See other pages where Star-shaped copolymers core-first method is mentioned: [Pg.57]    [Pg.253]    [Pg.27]   
See also in sourсe #XX -- [ Pg.868 ]



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Core first method

Core-first

Shaping methods

Star core-first method

Star-shaped

Star-shaped copolymers

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