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Copper chloride-Chlorotrimethylsilane

In the cyclic series several examples, as summarized above, have been provided. The diastereoselectivity, l or u, essentially can be controlled by the choice of the halide in the Grignard reagent and the additive, i.e., employing either organomagnesium bromide with copper(I) bromide and a phosphine, or organomagnesium chloride with copper(I) bromide and chlorotrimethylsilane (see also syn/anti selectivity in Section 1.1.1.2.). [Pg.555]

Metal-containing compounds, Zinc Compounds (Continued) (Carboethoxyalkyl)zinc iodide, 220 (Carboethoxyethyl)zinc iodide, 220 (Carboethoxypropyl)zinc iodide, 220 Chlorotrimethylsilane-Zinc, 82 (Cyanomethyl)zinc bromide, 221 Dibromomethane-Zinc-Copper(I) chloride, 93... [Pg.416]

A synthetic procedure for copper(I) thiolates that avoids the formation of Group 1 (IA) metal salts is the reaction of trimethylsilyl arenethioethers (Me3SiSAr) with copper(I) chloride (Eq. 7) (68, 69). From this reaction the only side product is volatile chlorotrimethylsilane, which can be easily removed in vacuo. [Pg.105]

See other pages where Copper chloride-Chlorotrimethylsilane is mentioned: [Pg.97]    [Pg.59]    [Pg.163]    [Pg.260]    [Pg.37]    [Pg.285]    [Pg.439]    [Pg.37]    [Pg.343]    [Pg.145]   
See also in sourсe #XX -- [ Pg.97 ]



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