Coordination compounds of Group

Coates, G.E., Kowala, C. and Swan, J.M. (1966) Coordination compounds of Group IB metals. I. Triethylphosphine complexes of Au(I) mercaptides. Australian Journal of Chemistry, 19, 539-545. 

D. HeUwinkel, Penta and hexa coordinated compounds of group V elements. Topics. Curr. Chem., 109, 1, 1983. 

SOME NOVEL COORDINATION COMPOUNDS OF GROUP IV METALS. 

B2 SOME NOVEL COORDINATION COMPOUNDS OF GROUP IV METALS, A.F. Reid and P.C. Wailes... 

Additional organogermanium derivatives with coordination compounds of Group I, IV and VI transition metals are listed in Table 83. 

Due to the relatively high acidities of their hydroxy groups, hydroxyazoles readily exchange their protons with metal ions, which leads to stabilization of metal derivatives of the hydroxy tautomeric forms in metal coordination compounds of 2(5)-oxoazoles [97UK434 98AHC(72)1]. A typical example is the mercury complex 361 [93JCS(D)1003]. 

The behaviour of polydentate ligands containing sulphinyl groups has received much less attention. Giesbrecht and Osorio203 have reported the coordination compounds of bivalent transition metal (Mn2+, Co2+, Ni2+, Cu2 +, Cu2+, Zn2+) perchlorates with 2,2 -sulphinyldiethanol (SDE). 

Table 4.2. Lewis-like oxidation numbers (n07L), formal d count, metal electron configuration (eep, Chp) and minimum and maximum coordination numbers (ncs) for low-spin normal-valent compounds of group 6-11 transition metals...

Figure 4.102 A comparison of coordinative ctmc hybrids (left) and nM 7rCo+ pi-backbonding interactions (right) for M(CO)3 compounds of group 6.

Since a molecule with a center of symmetry, such as one belonging to point groups D h (n even). Cntl (n even). Dtlll (n odd), O, and //, cannot have a dipole moment, no matter how polar the individual bonds (Chapter 3), dipole moments have proved to be useful in distinguishing between two structures Much of the classic chemistry of square planar coordination compounds of the type MA2B2 was elucidated on the basis of cis isomers having dipole moments and traps isomers having none (see Chapter 12). ... 

Coordination Compounds of Hetarenes with Group V Elements... 

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