Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Coordinates localized

Here u is the position of a layer plane and z is the position coordinate locally parallel to the director n, where n is parallel to the average molecular axis, which is assumed to remain normal to the layer plane, du/dz = e is the compressional (or dilational) strain. Thus, layer bending and layer compression are characterized by a splay (or layer-bend) modulus K and a compression modulus B. Other kinds of distortion present in nematics, such as bend or twisting of the director n, are not compatible with layers that remain nearly parallel, and hence are forbidden. Equation (10-36) is not invariant to rotations of frame, and its validity is limited to weak distortions a rotationally invariant expression has been given by -Grinstein and Pelcovits (1981).---------------------------------------------------------... [Pg.481]

Etzler (1983) has proposed a first-order theory of vicinal water based on the percolation theory treatment of bulk water developed by Stanley and Teixeira (1980a,b). Etzler assumes two distinct types of H-bond connectivity, namely, a perfect four-connected set of water molecules and the remainder, with three, two or one (or no) H-bonds. Based on the idea that two distinct populations of water molecule environments exist, Etzler calculated the increase in the amount of ice-like (four-coordinated) local environments and proposed that the tendency to create such more nearly tetrahedral arrangements is somehow induced by proximity to the surface. The vicinal water thus represents an enhancement of the ice-like structure. Etzler then calculated the density of the water in silica pores. This was... [Pg.179]

FEMA is not the only culprit a breakdown occurred on all levels of government. According to the National Response Plan that establishes a comprehensive all-hazards approach to enhance the ability of the United States to manage domestic incidents, local, state, and federal authorities are all designated specific responsibilities and duties. The mayor is responsible for coordinating local resources to address the full spectrum of actions to prevent, prepare for, and recover from major disasters, accidents or acts of terrorism. He/she requests state and, if necessary, federal assistance through the governor of the state when the jurisdiction s capabilities have been... [Pg.112]

The coordination, localization, stabilization and reduction of copper ions embedded in various zeolitic and oxidic materials were studied using EPR and TPR. Coordination poly-hedra and kind of ligands in the copper complexes after thermal treatment at 250 and 500 C has been evaluated and their relation to TPR results is shown. [Pg.223]

Coordination, localization and stabilization of transition metal ions in zeolitic materials, apart from activation conditions, depend on the structure and composition of the zeolite matrix. To evaluate the extent of such a matrix effect Cu +ions are used as a metal ion probe in this work, and copper ion-matrix interaction in different zeolites and oxides has been studied by EPR and TPR. ... [Pg.223]

This model can hardly be more unUke a universe that expands in three-dimensional Euclidean space. The special-relativistic requirement of foru -dimensional space, with the cru vature of general relativity superimposed, seems to demand that space-time has a minimum of five dimensions, which is equivalent to four-dimensional projective space, described by five homogeneous coordinates. Locally perceived three-dimensional space therefore is an illusion and extrapolation of local structure, beyond the Galactic borders, a gross distortion. [Pg.235]

Inserting Eq. [49] into Eq. [46] shows that the coordinates given by the method of undetermined parameters are accurate to 0(ht ). The error in the coordinates (local error) is of the 0(bt ) present in the basic Verlet scheme. Therefore, consistent with the preceding error analysis, no additional error is introduced in the method of undetermined parameters, and the constraints are exactly satisfied at every time step. If the approximate forces of constraints are desired, they can be computed a posteriori as... [Pg.102]

Figure 6.1. Sketch of the cell cross section and the system of coordinates. Local 2D models simulate single 2D element. 3D models usually deal with a single 3D element however, the situation with 3D models is rapidly changing and nowadays these models are able to simulate the whole cell. Along-the-channel models solve equations in the x-z plane. Figure 6.1. Sketch of the cell cross section and the system of coordinates. Local 2D models simulate single 2D element. 3D models usually deal with a single 3D element however, the situation with 3D models is rapidly changing and nowadays these models are able to simulate the whole cell. Along-the-channel models solve equations in the x-z plane.
The eigenvector associated to X represents the most probable direction of crossing the saddle point amongst all the trajectories joining the adjacent minima. Along this reaction coordinate, localized functions... [Pg.215]

X-ray or neutron diffraction IR and Raman spectroscopies, MNR EXAFS X-ray photoelectron spectroscopy (XPS) X-ray reflectometry Radial distribution and/or crystal phase Local symmetry, coordination Local symmetry, radial distribution, coordination Surfece arrangement (Section 5.8) Surface arrangement (Section 5.8)... [Pg.93]


See other pages where Coordinates localized is mentioned: [Pg.43]    [Pg.22]    [Pg.31]    [Pg.254]    [Pg.31]    [Pg.241]    [Pg.268]    [Pg.43]    [Pg.397]    [Pg.556]    [Pg.43]    [Pg.165]    [Pg.656]    [Pg.120]    [Pg.220]    [Pg.4]    [Pg.475]    [Pg.511]    [Pg.387]    [Pg.84]    [Pg.97]    [Pg.54]    [Pg.11]    [Pg.160]    [Pg.126]    [Pg.31]    [Pg.361]    [Pg.363]   
See also in sourсe #XX -- [ Pg.97 ]




SEARCH



Local coordinate

Local coordination

© 2024 chempedia.info