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Cooperative rotations

Another observed transition deals with the 1st and 2nd phenyl rings, which are attached to the 1st isopropylidene unit. Figure 66 shows that 02 of the 1st phenyl ring changes from 60° to - 50° between 55 and 80 ps, while 02 of the 2nd phenyl ring changes in the same direction exactly within the same duration. This is an in-phase cooperative rotation of the rings attached to the... [Pg.103]

This energy corresponds to the rest mass M°s = E°s/C20. In the context of the model of cooperative rotation, the soliton describes a correlated change in phases of the rotors of the chain appreciable phase changes are accumulated through the distance L c/ 0, which is greater than the lattice period because of condition (7.70). [Pg.255]

The cooperative rotations of the MnC>6/2 octahedra increase with decreasing radius of the... [Pg.275]


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See also in sourсe #XX -- [ Pg.253 , Pg.254 , Pg.255 , Pg.256 , Pg.257 , Pg.258 , Pg.259 ]




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Molecular rotation cooperative

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