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Cooperative pore filling

In real materials the pores are connected to one another and form a three-dimensional network. The interconnection of pores accounts for the cooperative character of adsorption phenomena. In capillary condensation the effect of the initiation of condensation in the wide pores appears after condensation in the narrow pores adjacent to them. The delay in desorption from the wider pores is stipulated by its blocking by the narrower ones. These cooperative effects cannot be allowed for by a model of unrelated pores the requirements for filling or emptying of a given pore depend not only on its own characteristics but on the characteristics of adjacent pores as well. [Pg.68]


See other pages where Cooperative pore filling is mentioned: [Pg.242]    [Pg.433]    [Pg.242]    [Pg.433]    [Pg.53]    [Pg.53]    [Pg.577]    [Pg.578]    [Pg.471]    [Pg.474]    [Pg.338]    [Pg.594]    [Pg.190]    [Pg.29]    [Pg.14]    [Pg.20]    [Pg.63]    [Pg.125]    [Pg.132]    [Pg.111]    [Pg.13]    [Pg.470]    [Pg.471]    [Pg.99]    [Pg.331]    [Pg.490]    [Pg.416]    [Pg.399]    [Pg.51]    [Pg.388]    [Pg.15]    [Pg.331]    [Pg.3]    [Pg.437]   
See also in sourсe #XX -- [ Pg.242 ]




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