Cooling electrical properties

A polymorph is a solid crystalline phase of a compound resulting from the possibility of at least two different crystal lattice arrangements of that compound in the solid state [42], Polymorphs of a compound are, however, identical in the liquid and vapor states. They usually melt at different temperatures but give melts of identical composition. Two polymorphs of a compound may be as different in structure and properties as crystals of two different compounds [43,44], Apparent solubility, melting point, density, hardness, crystal shape, optical and electrical properties, vapor pressure, etc. may all vary with the polymorphic form. The polymorphs that are produced depend upon factors such as storage temperature, recrystallization solvent, and rate of cooling. Table 2 suggests the importance of polymorphism in the field of pharmaceutics [45],... 

Metal Oxide-Polymer Thermistors. The variation of electrical properties with temperature heretofore described can be used to tremendous advantage. These so-called thermoelectric effects are commonly used in the operation of electronic temperature measuring devices such as thermocouples, thermistors, and resistance-temperature detectors (RTDs). A thermocouple consists of two dissimilar metals joined at one end. As one end of the thermocouple is heated or cooled, electrons diffuse toward... 

Typical values of electrical properties of the homopolymer without additives and treatments are in the Table 3.8. The values can be substantially changed by the type of cooling and post-treatments, which determine the morphological state of the polymer. Dielectric constants as high as 17 have been measured on oriented samples that have been subjected to high electrical fields (poled) under various conditions to orient polar crystalline form.74... 

It is generally considered that the electrical properties of polymers and composites tend to increase their values to advantageous regions on cooling to cryogenic temperatures. 

Table 9.2. Electrical properties of epitaxial layers with Ga doping versus solvent and cooling rate. Growth temperature was 1,050°C [69]...

It was discovered that a number of PVDF film properties, including electrical, could be altered by the extrusion and orientation conditions.The relationship between the extrusion and orientation process and the electrical properties of the film are important because of the application of PVDF films in miniaturized capacitors which are used in apparatus such as defibrillators. To compare the properties, extruded film, while in molten state, was brought in contact with chilled rollers at 80°C and cooled rapidly. The oriented film was stretched at 150°C in the longitudinal direction by a stretch ratio of 3.5, that is, its original length was increased by 3.5 times [Eq. (6.6)]. The dielectric constant and dissipation factor were measured as seen in Table 6.8. Orientation increased the dielectric constant and reduced the dielectric loss... 

Recently, xenon has been used as a nonreactive probe of surface structure. As long as the surface can be cooled to a low enough temperature to adsorb this inert gas atom, its local interaction with surface sites of different structure yields large enough variations in its heat of adsorption to be used as a probe of the surface structure. As we shall see in the chapter on electrical properties of surfaces, the surface electric dipole varies from site to site, depending on the structure of the site. This electric dipole influences the polarizability and thus the bonding of adsorbed atoms or molecules at that site. 

There are various methods of the glass transition temperature evaluation based on temperature dependence of polymer physical properties in the interval of glass transition 1) specific volume of polymer at slow cooling (dilatometric method) 2) heat capacity (calorimetric method),3) refraction index (refractometric method) 4) mechanical properties 5) electrical properties (temperature dependence of electric conductivity) or maximum of dielectric loss 6) NMR ° 7) electronic paramagnetic resonance, etc. 

Term used to describe a part immediately after it is removed from a mold and allowed cooling down. All physical, chemical, and electrical property tests are performed on nonconditioned test bars and the results recorded on the data sheets. Parts and test bars in this DAM state are felt to be their weakest in some properties as they have not had time to conditirm or relieve the molded-in stresses. 

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