Controlling Factors for nanocomposite formation

The thermodynamic spontaneity of the interacalation process is determined by an interplay of entropic and enthalpic factors [38, 39]. The confinement of the polymer inside the interlayer results a decrease in the overall entropy of the polymer chains. However, the entropic penalty may be compensated by the increased conformational freedom of the tethered surfactant chains in a less confined environment, as the layers separate out. Even then, there is an overall decrease in entropic factor as the increase in gallery height is very small. Thus the degree of layer separation depends on the establishment of very favorable polymer surface interaction to over come the penalty of polymer confinement. There are two different types of interactions, unfavorable apolar interaction and the favorable polar interaction, which originates from the Lewis acid/Lewis base character of the layered silicates. Thus depending on the interactions and entropic factors three possible equilibrium states are generated namely immiscible (conventional), intercalated and exfoliated. 

For a highly hydrophobic polymers like polypropylene (PP), the modification of clay gallery with an onium ion having the highest possible number of carbon atoms 

I I j j I I I Exua-galteiy viioous force Clay layer — i -J 

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