Continuous Fourier transform

As with the continuous Fourier transform, we could treat the equations of the discrete Fourier transform (DFT) completely independently, derive all the required theorems for them, and work entirely within this closed system. However, because the data from which the discrete samples are taken are usually continuous, some discussion of sampling error is warranted. Further, the DFT is inherently periodic, and the limitations and possible error associated with a periodic function should be discussed. 

To illustrate more appropriately the relationship between the (continuous) Fourier transform and the DFT, the alternative form given in Chapter 1 will be employed. Accordingly, we define this transform as... 

Thus, in order to remove illumination effects we first need to transform the input image to frequency space using a Fourier transform. The one-dimensional continuous Fourier transform is defined as (Bronstein et al. 2001)... 

This is simply a restatement of Bragg s law, since (Qt2K)d = Sd= 2s sin Q/X. The interference function for a stack of membranes will thus consist of a series of sharp peaks located at points S = li/d in reciprocal space. One can show that the peaks of the interference function will have widths on the order of VNd and amplitudes N. Therefore, if the number of membranes in the stack is large, the peaks are very narrow, so the interference function samples the continuous Fourier transform of the membrane electron density function at... 

As remarked previously, a crystal acts to decompose the continuous Fourier transform of the electron density in the unit cells into a discrete spectrum, the diffraction pattern, which we also call the weighted reciprocal lattice. Thus a crystal performs a Fourier analysis in producing its diffraction pattern. It remains to the X-ray crystallographer to provide the Fourier synthesis from this spectrum of waves and to recreate the electron density. 

Because the observed diffraction pattern is a product of the diffraction patterns from the two distributions, what is observed at each nonzero point in the combined transform, or diffraction pattern determined by the periodic point lattice in Figure 5.8c, is the value of the Fourier transform at that point from the continuous distribution in Figure 5.8a. That is, the combined diffraction pattern samples the continuous Fourier transform of the object making up the array, that of Figure 5.8b, but only at those discrete points permitted by the array s periodic, discrete transform seen in Figure 5.8d. 

The calculation of the Fourier space contribution is the most time consuming part of the Ewald sum. The essential idea of P M is to replace the simple continuous Fourier transformations in (3) by discrete Fast Fourier Transformations, that are numerical faster to calculate. The charges are interpolated onto a regular mesh. Since this introduces additional errors, the simple Coulomb Green function as used in the second term in (3), is cleverly adjusted in... 

Before we have a quick look at three of the most important transform methods, we should keep the following in mind. The mathematical theory of transformations is usually related to continuous phenomena for instance, Fourier transform is more exactly described as continuous Fourier transform (CFT). Experimental descriptors, such as signals resulting from instrumental analysis, as well as calculated artificial descriptors require an analysis on basis of discrete intervals. Transformations applied to such descriptors are usually indicated by the term discrete, such as the discrete Fourier transform (DFT). Similarly, efficient algorithms for computing those discrete transforms are typically indicated by the term fast, such as fast Fourier transform (FFT). We will focus in the following on the practical application — that is, on discrete transforms and fast transform algorithms. 

Two further aspects of Fourier transformation with respect to NMR data must be mentioned. With quadrature detection a complex Fourier transformation must be performed, there is a 90° phase shift between the two detectors and the sine and cosine dependence of the sequential or simultaneous detected data points are different. In addition because the FID is a finite number of data points, the integral of the continuous Fourier transform pair must be replaced by a summation. 

Thus, the adjoint relationship, expressed by the matrix G, is particularly simple. In quantum mechanics the coefficients ak have an important interpretation since they represent the amplitude of the wave function in momentum space. Equations (23) and (24) are direct analogues to the continuous Fourier transformation, which changes a coordinate... 

As stated previously, with most applications in analytical chemistry and chemometrics, the data we wish to transform are not continuous and infinite in size but discrete and finite. We cannot simply discretise the continuous wavelet transform equations to provide us with the lattice decomposition and reconstruction equations. Furthermore it is not possible to define a MRA for discrete data. One approach taken is similar to that of the continuous Fourier transform and its associated discrete Fourier series and discrete Fourier transform. That is, we can define a discrete wavelet series by using the fact that discrete data can be viewed as a sequence of weights of a set of continuous scaling functions. This can then be extended to defining a discrete wavelet transform (over a finite interval) by equating it to one period of the data length and generating a discrete wavelet series by its infinite periodic extension. This can be conveniently done in a matrix framework. 

In this formula, the sums on G and Gy correspond to continuous Fourier transforms on the reciprocal variables kx and ky of x and y, respectively, writ-... 

The continuous Fourier transform (CFT) of a real or complex continuous... 

Discrete Fourier transform inherits important properties of continuous Fourier transform. In addition, we can add data point by point and results point by point. Thus, we can use another simple mathematical function to modify the data series as well as the results series independently. 

The point of departure for the EFT from the continuous Fourier transform is the discrete Fourier transform (DFT). The DFT of an interferogram of N points to produce a spectmm of N points may be written as ... 

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