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Containing Organic Bridging Groups

PMO precursors can be divided roughly into three classes bis-silylated compounds, which contain (1) short-chained alkylene or alkenylene groups as the organic bridge, (2) those with aromatic bridges, and (3) branched or cyclic multi-silylated compounds. An overview of the constitution formulae of PMO precursors is provided in Figure 3.11. [Pg.58]

Fc2(CO)9 is a sparingly soluble molecule in most organic inert solvents the molecule contains three bridging carbonyl groups connecting the two Fe(CO)3 units, and it can be described as (OC)3Fe(/u.2-CO)3Fe(CO)3. The iron iron distance is 2.523 A, according to an X-ray diffiaction study. ... [Pg.646]

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Bridge groups

Bridging group

Organic groups

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