Conductometric titration precipitation reactions

Advantages and Limitations of Radiometric Titrations. Radiometric detection of the equivalence point is a general method that does not depend on the chemical reaction employed. This contrasts with other methods of detection, which depend on specific chemical or physical transitions at the equivalence point. Amperometric titrations are applicable only to electrochemically active systems conductometric titrations apply only to ionic solutions, and so on. In principle, any titration system in which a phase separation can be effected is amenable to radiometric detection, provided there exist suitable radioactive labels. The major limitation of the method is the requirement for phase separation. In precipitation titrations, the phase separation is automatic and the method is well suited to this class of titrations. For other classes of titrations, special phase-separation methods, such as solvent extraction, need to be applied. At the present time, the method suffers from a lack of phase-separation techniques suitable for continuous monitoring of the titration curves. 

Other types of titrations including those of mixtures of acids, precipitation titrations, such as silver with halides, and complex reactions are also adaptable to conductometric titration methods and frequently yield better analytical results than the... 

The course of precipitation and complexometric titrations can also be followed conductometrically, but changes of slope are generally less pronounced. Redox reactions are difficult to follow because of the high... 

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