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Conducting polymers charging-discharging mechanism

The conducting polymers show a significant non-faradaic component of the electrochemical mechanism. The essential differences of faradaic and non-faradaic systems in equilibrium behavior, trends of galvanostatic charge - discharge curves and cyclic voltammograms have been shown, and criteria for the identification of these mechanisms are proposed [8],... [Pg.319]

As already mentioned, the principle of electroneutrality must be fulfilled in charged polymers. Consequently, in freshly prepared p-doped polymers, anions must compensate the positive charges within the polymeric chains. However, spectroelectrochemical studies [114], electrochemical quartz microbalance (EQMC) measurements [115], and SIMS and XPS measurements [116] on the mechanism of ion transport during charging and discharging of conducting polymers prove that discharging involves not only the expulsion of... [Pg.1330]


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See also in sourсe #XX -- [ Pg.198 ]




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Charge conductivity

Charge-discharge mechanism

Charge/discharge

Conductance mechanisms

Conducting Mechanisms

Conducting polymers conduction mechanism

Conduction charge

Conductive polymers conduction mechanisms

Conductivity mechanism

Discharge mechanisms

Polymer mechanical

Polymer mechanism

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