Compositional dependence of glass

Figure 3. Composition dependence of glass transition temperature of PVPMPS-18/PVPr blends.

Gupta R K. and Mauro J. C., Composition dependence of glass transition temperature and fragility. I. A topological model incorporating temperature-dependent constraints. /. Chem. Phys., 130, 094503/1-094503/8 (2009). 

Kim D, Lee BJ, Kim NJ, Prediction of composition dependency of glass-forming ability of Mg-Cu-Y alloys by thermodynamic approach , Scripta Materialia, 2005 52 969-972. 

Schult K. A., and Paul D. R., Techniques for Measurement of Water Vapor Sorption and Permeation in Polymer Films, J. Appl. Polym. Sci, 1996, 61, 1865-1876. Mattera V. D., Jr., and W. M. Risen, Jr., Composition dependence of Glass Transition Temperature of Sulfonated-Polystyrene lonomers, J. Polym. Sci., Part B, Polym. Phys., 1986, 24, 753. 

Figure 6. Composition dependence of the glass-transition temperature Tg for bulk amorphous Pd Cugo. xPzo-...

Fig. 11.3 Compositional dependence of hydroxyapatite formation on the glasses in the system Ca0-Si02-P205. Soaking period ...

Ohtsuki, C., Kokubo, T., Takatsuka, K. and Yamamuro, T. (1991) Compositional dependence of bioactivity of glasses in the system CaO-... 

O. Isatd, The dependence of glass-electrode properties on composition. 

Recently, alternative theoretical expressions have been developed by using classical thermodynamic treatments to describe the compositional dependence of the glass transition temperature in miscible blends and further extended also to the epoxywater systems 2S,27). The studies carried out on DGEBA epoxy resins of relatively low glass transition have shown that the plasticization induced by water sorption can be described by theoretical predictions given by ... 

Figure 20.7 The composition dependence of ionic conductivity and DBOP in the 60Li2S 0.4(xAlSi 5(100-x)SiS2) glasses.

This leads to a dependence of glass transition temperature on composition... 

The spontaneous mixing of the two polymers will transpire at a rate which reflects the degree of miscibility of the system. As X approaches the critical value for phase separation, "thermodynamic slowing down" of the interdiffusion will occur [12]. The rate of increase of the scattering contrast reflects the proximity of the system to criticality, as well as the strong composition dependence of the glass transition temperature of the blend. Extraction of a value for either the self diffusion constants [13,14] or the interaction parameter is not feasible from the presently available data. 

Figure 2. Dependence of glass transition temperature, T , on composition for samples cured with schedule A.

Figure 3. Dependence of glass transition temperature on composition of samples cured at ambient temperature and following subsequent heat-up. Key to cure schedule -----------------, A , B and B + heat-up to 180°C.

Figure 13.17 Compositional dependence of the A1 MAS NMR spectra in AlxTcioo-x (17 < X < 30) glasses (After Murugavel and Asokan, 1998).

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