Complexes organometals

This provides new options for synthesis and purification of sensitive oiganometallic complexes N. Spetse-ris, S. Hadida, D. P. Curran, T. Y. Meyer, "Organic/fluor-ous phase extraction A new tool for the isolation of organometallic complexes , OrganometaL 1998,171458. 

Cfo, CjJ, and CJ being the number of centers with a free vacancy, with a coordinated monomer, and with a complexed organometal, respectively. It is assumed that the centers denoted as C are detectable employing selective stoppers, while the total C s are determined by N- and MPB-methods. This concept is supported by the observation that... 

An important question has yet to be answered are rr-complexed organometal systems capable of controlling the stereochemistry of 1,2 shifts The n-(arene) chromium tricarbonyl complexes of threo- and eryrfcro-3-phenyl-2-butyl mesylates, (900) and (901), and of e/7fhro-2-phenyl-3-pentyl mesylate (902) have been aceto-... 

G.I.Dzardimaliyeva, B.S.Selenova, T.I.Ponomareva et al., Complex Organometal Catalysts of Olefin Polymerization, Chemogolovka, Institute of Chem. Phys, USSR Academy of Sciences, N10, 55 (1986). 

Llamazares A, Schmalle HW, Berke H (2001) Ligand-assisted heterolytic activation of hydrogen and silanes mediated by nitrosyl rhenium complexes. Organometallies... 

Liang FP, Jacobsen H, Schmalle HW, Fox T, Berke H (2(X)0) Carbonylhydridonitrosyltris (trimethylphosphine)molybdenum(O) an activated hydride complex. Organometallies 19 1950-1962... 

Brunner, H. (1986) Enantioselective catalysis by transition metal complexes. /. Organomet. Chem., 300, 39. 

This classified bibliography of organic and organometallic crystal structures covers the period 1935-1969 and provides references to over 4,000 compounds whose structures were analysed by X-ray or neutron-diffraction methods. Volume 1 deals with general organic structures and Volume 2 with complexes, organometals and organo-metalloids. 

Huynh HV, Jothibasu R. Syntheses and catalytic activities of Pd(II) dicarbene and hetero-dicarbene complexes. Organomet Chem. 2011 21 3369-3375. 

N. Miyaura, Cross-coupling reaction of organoboron compounds via base-assisted transmetalation to palladium(ii) complexes,/. Organomet Chem., 2002,653(1-2), 54-57. 

Burck S, Gudat D, Nieger M (2009) Cleavage of polarized P—P bonds in n-heteroeyelic diphosphines in reactions with metal olefin complexes. Organometallies 28 1447... 

Obviously, if the step in which T reacts is rate-controlling, then the overall reaction rate depends in some way upon the concentration and identity of T. This dependence may take the form of a direct proportionality to [T], but more complex forms have been given in the preceding paragraphs. If the reaction of an intermediate with a trap is faster than the step generating the intermediate, on the other hand, then the rate may not depend on either the concentration or the identity of the trap. If, for example, an organometal (RM) undergoes a slow, homolytic decomposition,... 

Alkynyl complexes Fischer EO, Kalder HJ (1977) J Organomet Chem 131 57... 

For a review on metal-ketene complexes see Geoffroy GL, Bassner SL (1988) Adv Organomet Chem 28 1... 

Davis, M. 1. Speed, C. S. (1970) Gas-phase electron diffraction studies of some iron carbonyl complexes, J. Organomet. Chem. 21,401-413. 

Cotton, F. A. LaPrade, M. D. (1972) The structure of a novel complex derived from cyclooctadienetricarbonylruthenium, J. Organomet. Chem. 39,345-354. 

W. Beck Organometal Chem. Complex metal fulminates 32 ... 

Fig. 11. Proposed structure for (C5H5)2Sn -MX3 complexes (M = B, Al). Reprinted with permission from J. Organomet. Chem. 108, 38 (1976). Copyright by Elsevier Sequoia S.A.

Phenylcopper -triphenylphosphine complexes Camus, A. el al., J. Organomet. Chem., 1980, 188, 390... 

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