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Complexes of S-Donors

The thiocyanate (Ph4P)3[Rh(SCN)6] is S-bonded, with Rh—S 2.372 A however, linkage isomers [Rh(NCS) (SCN)6 ]3 exist, separable by chromatography [103], [Pg.123]

A series of sulphide complexes can be made by refluxing the rhodium trihalide with the appropriate organic sulphide in methanol or ethanol  [Pg.123]

Tris-chelates with bidentate S-donors are made conventionally (Rh—S 2.368 A for Rh(S2CNEt2)3) [Pg.124]

The dithioacetylacetonate is made by preparing the ligand in situ the stable red crystals have 6-coordinate rhodium (Rh-S 2.314-2.333 A  [Pg.124]

Thiacrown ether and related systems also tend to involve octahedrally coordinated rhodium(III) [107]. [Pg.125]

A number of lanthanide thiolates have been synthesized in recent years and are discussed in Section 4.4.3. [Pg.46]

See other pages where Complexes of S-Donors is mentioned: [Pg.123]    [Pg.147]    [Pg.147]    [Pg.225]    [Pg.256]    [Pg.288]    [Pg.296]    [Pg.296]    [Pg.139]    [Pg.164]    [Pg.164]    [Pg.243]    [Pg.275]    [Pg.307]    [Pg.315]    [Pg.315]    [Pg.123]    [Pg.147]    [Pg.147]    [Pg.225]    [Pg.256]    [Pg.288]    [Pg.296]    [Pg.296]    [Pg.46]    [Pg.4231]    [Pg.123]    [Pg.147]    [Pg.147]    [Pg.225]    [Pg.256]    [Pg.288]   


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Donor complex

S complex

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