Sulphide complexes

Alkyl sulphide complexes can be synthesized from RuC13 and R2S in ethanol at reflux [114b,c] ... 

A series of sulphide complexes can be made by refluxing the rhodium trihalide with the appropriate organic sulphide in methanol or ethanol ... 

Alkene complexes Alkynyl complexes Ammine complexes Aqueous chemistry Arsine complexes Auranofin Auride ion Aurophilicity Binary compounds Bond lengths acetylacetonate complex alkyls and aryls ammine complexes carboxylates cyanide complexes dialkyl sulphide complexes dithiocarbamates to gold... 

A convenient route to both saturated and unsaturated acylsilanes lies in the hydroboration-oxidation of alkynylsilanes (Chapter 7). Recent improvements (6) to this method involve the use of the borane-dimethyl sulphide complex for hydroboration, and of anhydrous trimethylamine A-oxide for the oxidation of the intermediate vinyl boranes. 

Mountain BW, Seward TM (1999) The hydrosulphide/sulphide complexes of copper(I) experimental determination of stoichiometry and stability at 22°C and reassessment of high temperature data. Geochim Cosmochim Acta 63 11-29... 

The sulphide ligands containing one butenyl group form chelate complexes with platinum(II) and palladium(II) halides. The chelated butyl pentenyl sulphide complexes could only be obtained for platinum-(II). The compounds containing two group VI atoms functioned as bidentate ligands by donation from the two sulphim atoms only. All these chelated olefinic sulphide complexes react with simple monodentate... 

Borane-methyl sulphide complex 4-Toluenesulfonyl chloride cis-3,5-Cyclohexadiene-l,2-diol l -Dynamax 83,123-6 column Silver oxide Sodium hydride Palladium on charcoal Tetrabenzylpyrophosphate... 

The high stability of the sulphide and phosphine complexes formed by soft acceptors is entirely due to strongly negative values of AH0, exactly as expected. For all phosphine complexes, A S0 is in fact < 0, i.e. counteracting the reaction. For the only sulphide complex of a soft acceptor so far investigated, that of CHaHg+, dS° is only slightly > 0, i. e. of little importance for the formation of the complex. 

Regiospecific oxidation of the 3-hydroxy-group of methyl fusidate has been accomplished by use of the Corey reagent (one equivalent of AT-chlorosuccinimide-dimethyl sulphide complex). 

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