Cobalt tetraphenylporphyrinato

Allylperoxy)(pyridyl)( texo-tetraphenylporphyrinato)cobalt(lll) (KEBMIN) [A,A -(Dipropylenetriamine)bis(salicylideneiminato)][2,4,6-tri-tert-butyl-l-peroxy)quinolato]cobalt(lll) (SCQUCO) 1.401 1.408 107.5 128... 

Allylperoxy)(pyridyl)(mexo-tetraphenylporphyrinato)cobalt(III) (KEBMIN) 1.401 1.408 107.5 128... 

Incorporation of (meso-tetraphenylporphyrinato)cobalt(II), [Co(tpp)], into plasma polymer thin films for the possible use as dioxygen-selective permeable membranes has also been reported (91). Comparisons to... 

The endoperoxide transfers a sulfur atom to alkenes forming thiiranes (episulfides) the process is made more efficient in the presence of the tetraphenylporphyrinato cobalt(ll) complex <1996CC177>. With cyclic alkynes such as cyclooctyne, an interesting thiirenium ion intermediate could be observed <2002JA8316>. 

P. Neta, V. Grebel, and H. Levanon, One-Electron Oxidation of Chlorophyll a and (Tetraphenylporphyrinato)cobalt(II) by Various Metalloporphyrin Cation Radicals. Kinetic Spectrophotometric Studies, J. Phys. Chem., 85 (1981) 2117. 

The formation of phenoxy radicals upon oxidation from substituted phenols has been studied by the ESR technique, using nitrosodurene as spin trap [52]. Chloro(5,10,15,20-tetraphenylporphyrinato)cobalt(III) and its Ti-cation radical were used to promote the reaction. The phenols studied reacted with the cation radical but some of them interacted only with the complex. The reaction is pictured as involving electron transfer from the phenolate, mediated by an axially coordinated chloro ligand. 

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