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Cobalt complexes base-catalysed hydrolysis

Base-catalysed hydrolysis of cobalt(lll) ammine complexes 335... [Pg.335]

Stable cobalt (III) ion complexes with which ligand exchange does not occur were prepared by the scheme of equation (32) (Alexander and Busch, 1966 Buckingham et al., 1967a, b, c), and were isolated and characterized. Large rate enhancements in hydrolysis are observed in comparison with the uncomplexed esters for attack of Hj O at pH 1-4, but it is of greatest interest that the reactions are markedly catalysed by general bases. It has been observed that... [Pg.68]


See other pages where Cobalt complexes base-catalysed hydrolysis is mentioned: [Pg.227]    [Pg.304]    [Pg.115]    [Pg.244]    [Pg.178]    [Pg.132]    [Pg.146]    [Pg.75]    [Pg.198]   
See also in sourсe #XX -- [ Pg.989 ]




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