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Oxidative cluster closure reactions

Synthetic routes to metalloboranes are briefly summarized. Two specific aspects of the field are selected for more detailed comment (i) the occurrence of exopolyhedral cycloboronation of P-phenyl groups (ii) oxidative cluster closure reactions. These topics are illustrated by reference to reactions of closo-BioHio nido-B9H12 and arachno-BoHiU" with a variety of Ir1 complexes, and several novel metalloborane cluster geometries (as determined by X-ray diffraction analysis) are described, notably nido-TIr(BoHi )H (PPh3)2], i so-ni do-[ IrC(OH)B8H6(OMe) (CgH PPh )... [Pg.321]

See other pages where Oxidative cluster closure reactions is mentioned: [Pg.329]    [Pg.170]    [Pg.93]    [Pg.166]    [Pg.83]    [Pg.4]    [Pg.59]    [Pg.22]   


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