Chlorotitanium triphenoxides

Prepared from chlorotitanium triphenoxide and CH3Li in situ reaction with 124 in ether at... 

The reaction of a wide variety of functionalized epoxides containing esters, amides and acetals with chlorotitanium triphenoxide and allylmagnesium chloride provides exclusive reaction at the more substituted carbon <05T6726>. The use of protected chiral epoxides, 54 and 56, with the same reagent system provides a facile route into chiral quaternary centers, 55 and 57. 

Reacting the chlorotitanium triphenoxides XXII, XXin, and XXIV with V in cyclohexane or toluene at ambient temperature yields mononuclear Tbf... 

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See also in sourсe #XX -- [ ]

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