Chlorohydrido complexes

Iridium-containing complexes have also been studied over the period reviewed <2000ICC511, 2002OM5775>. Treatment of the methoxy-functionalized ligand 98 with IrCl3 H20 in 2-propanol/water gave the chlorohydrido complex 99 (Equation 32). 

In this section, we will review the nature and chemical reactivities of several kinds of ruthenium complexes under the following headings ruthenium carbonyl complexes, dichlororuthenium complexes, chlorohydrido complexes, dihydridoruthenium complexes, ruthenium complexes with chiral ligands, ruthenium complexes with cyclopentadienyl ligands, and ruthenium arene/diene complexes. 

The reactions of arenediazonium salts with (rans-chlorohydrido-bis(triethylphosphine)platinum(II)1 give aryldiimide complexes which are precursors to new arylazoplatinum compounds2 and... 

CIBF4lrN2P2Cj, Iridium (III), chloro-(dini-trogen)hydrido[tetrafluoroborate-(1 — )]bis(triphenylphosphine)-, 26 119 CIBFJrOP2Cj7H], Iridium(III), carbonyl-chlorohydrido[tetrafluoroborato(l - ))-bis(triphenylphosphine)-, 26 117 ClBFjIrOPjCaHj, Iridium(III), carbonyl-chloromethyl[tetrafluoroborato(l — )]-bis(triphenylphosphine)-, 26 118 CICH], Methane, chloro-, osmium complex, 27 205... 

The essential series of reactions leading to hydrogen-deuterium exchange in aromatic phosphines can be illustrated with the chlorohydrido-fn s-triphenyl-phosphineruthenium(II) complex, 19 ... 

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