Chlorofluorosulfonium salts

Mixed chlorofluorosulfonium salts are prepared by oxidative halogenation of acidic secondary sulfonium salts [Eq. (4.52)] or oxidative fluorination with... 

Further reactions between XeF+MFg" (M = As, Sb) and the sulfanes SCI2 (16) and CF3SCI (77) led to the mixed halogenated chlorofluorosulfonium salts (Figure 1). Attempts to obtain single crystals of these compounds failed due to a strong tendency towards disproportionation, even in the solid state. For this reason, in the... 

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See also in sourсe #XX -- [ ]

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