2-Chloroallyl diethyldithiocarbamate

Two dithiocarbamates, sodium methyldithiocarbamate (metham, SMDC, 2) and 2-chloroallyl diethyldithiocarbamate (sulfallate, CDEC, 3) have been introduced as herbicides. These compounds were developed before the thiocar-bamate herbicides discussed in the preceding chapter. 

The reaction of an aqueous solution of sodium dlethyldithlocarbamate with 2,3-dlchloro-l-propene at 50-60 C afforded a 96% yield of 2-chloroallyl diethyldithiocarbamate, known by the tradename Vegadex (34). Since Vegadex was the first chloroalkenyl disubstituteddithio-carbamate synthesized, D Amico and Harman were granted three patents (35-37) covering both composition of matter and use as a herbicide. 

S(chloroallvl)Thio- and Dithiocarbamates (S-(2,3-dichloroallyl) diisopropylthiocarbamate, Avadex (IX) S- 2,3,3 trichloroallyl) diisopropythiocarbamate, Avadex BW(X) 2-chloroallyl-N,N-diethyldithiocarbamate, Sulfallate(XI)). 

SYNS CDEC CHLORALLYLDIETHYLDITHIO-CARBAMATE 2-CHLOROALLYL DIETHYLDITHIO-CARBAMATE 2-CHLOROALLYL-NA -DIETHYLDITHIOCARBAMATE 2-CHLORO-2-PROPENE-1-THIOL DIETHYLDITHIOCARBAMATE 2-CHLORO-2-PROPENYL DIETHYLCARBAMO-DITHIOATE CP 4572 DIETHYLCARBAMO-DITHIOIC ACID 2-CHLORO-2-PROPENYL ESTER DIETHYLDITHIOCARBAMIC ACID-2-CHLOROALLYL ESTER NCI-C00453 SULFALLATE THIOALLATE VEGADEX VEGADEX SUPER... 

DIETHYLDITHIOCARBAMATE SODIUM see SGJOOO DIETHYLDITHIOCARBAXnC ACID-2-CHLOROALLYL ESTER see CDO250 DIETHYLDITHIOCARBAMIC ACID SELENIUM(II) SALT see DJD400... 

A/iAf-Diethyldithiocarbamic acid, 2-chloroallyl ester Tetrachloroethylene Perchloroethylene Carbon tetrachloride Tetrafluoroethylene... 

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