Chlorine tnfluonde

Polymer-bound phenyliodine difluoride, which also has been used as a reagent to add fluorine to alkenes, can be prepared by the addition of xenon difluonde to the polymer [134, 135 136] Methyl iodide is converted to trifluoro methyliodine difluonde by treatment with fluorine at -110 °C [137] Perfluoro-alkyliodine tetrafluondes could be synthesized from the perfluoroalkyliodme difluorides and fluorine 38 or chlorine tnfluonde [759] Perfluoroalkyl [140] and perfluoroary 1 [141] iodides are oxidized to the corresponding iodine difluondes by chlorine trifluoride. 

Similar preference in replacement by fluorine of tertiary versus secondary and secondary versus primary hydrogens is observed in the fluonnation of alkanes with chlorine tnfluonde in 1,2-difluorotetrachIoroethane at room temperature (Table 3). Skeletal rearrangements accompany the fluorination [77]... 

Catalyst, alumina, 34, 79, 35, 73 ammonium acetate, 31, 25, 27 boron tnfluonde etherate, 38, 26 copper chromite, 31, 32, 36, 12 cupric acetate monohydrate, 38, 14 cuprous oxide silver oxide, 36, 36, 37 ferric nitrate, hydrated, 31, 53 phosphoric acid, 38, 25 piperidine, 31, 35 piperidine acetate, 31, 57 Raney nickel, 36, 21, 38, 22 sulfuric acid, 34, 26 Catechol, 33, 74 Cetylmalonic acid, 34, 16 Cetylmalonic ester, 34,13 Chlorination, by sulfuryl chloride, 33, 45, 37, 8... 

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