Fluorosulfate, chlorine

A peculiar reaction of perfluoroalkyl halides with chlorine fluorosulfate yields perfluoroalkyl fluorosulfales [iS (equation 17)... [Pg.450]

Chlorine fluorosulfate, 3975 (Chlorocarbonyl)imidosulfur difluoride, 0318 iV-(Chlorocarbonyloxy)trimethylurea, 1924... [Pg.8]

Chlorine fluorosulfate, 3969 (Chlorocarbonyl)imidosulfur difluoride, 0317 /V-(Chlorocarbonyloxy)tri methyl urea, 1918... [Pg.2213]

Reaction with PFIB is slow, and even after three weeks at 20 °C the yield of additional product does not exceed 27.4%. Iodine and chlorine fluorosulfates readily add across the C=C bond of F-ketene to give the corresponding acyl-fluorosulfates [8,107], for example ... [Pg.68]

CIFO3S, Chlorine fluorosulfate, 24 6 CIF2NS, Imidosulfurous difluoride, chloro-, 24 18... [Pg.250]

O3CIFS, Chlorine fluorosulfate, 24 6 O3FPC4HK, Phosphofluoridic acid, diethyl ester, 24 65... [Pg.282]

Chlorine fluorosulfate is a pale yellow liquid that solidifies at —84.3° and boils at 43.4°. The IR spectrum of the gas has bands at 1481 (vs), 1248 (vs), 855 (vs), 831 (ms, sh), 703 (ms), 572 (ms), and 529 (m) cm (stainless steel cell with AgQ windows). Chlorine fluorosulfate is the only known practical intermediate for the synthesis of chlorine perchlorate, ClOClOj, and it is easily photolyzed in Pyrex at room temperature to provide FOjSOOSO F in high yield." Chlorine fluorosulfate reacts violently with water. [Pg.8]

G. H. Sprenger, K. J. Wright, J. M. Shreeve, Inorg. Chem. 1973, 12, 2890-2893. Polttf additions of chlorine monofluoride and chlorine fluorosulfate to fluorinated isocyanates. [Pg.69]

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