Chloramidation, of tertiary amines

The chloramidation of tertiary amines by introducing gaseous chloramide (chloramine) into the anhydrous amine or a solution of the amine in an inert solvent results in the formation of 1,1,1-trisubstituted hydrazonium chlorides. It has been found that a similar chloramidation reaction with tertiary phosphines can be made to yield analogous compounds of the general formula [R3PNH2]C1, i.e., F,P,P-trisubstituted aminophosphonium chlorides. The following aminophosphonium chlorides were prepared by this reaction P,P,P-triphenyl P,P,P-tri-n-butyl P-phenyl-P,P-(cyclotetramethylene) and P-phenyl-P,P-(cyclopenta-methylene). The methodforthe preparation of (triphenyl)-aminophosphonium chloride is given as representative of the procedure. 

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See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

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