Chiral Frustrated Lewis Pairs as Catalysts

There is no doubt that hydrogen gas is the best hydrogen source for hydrogenation in terms of both atom economy and cost economy. However, usually, certain 

2 FI2 as a Terminal Flydrogen Source Combined Hydrogenation by Organocatalysis and Metal Catalysis 

1 (a) T. Ohkuma, M. Kitamura, and R. Noyori (2000) Asymmetric hydrogenation, in Catalytic Asymmetric Synthesis, 2nd edn (ed. I. Ojima), John Wiley Sons, Inc., New York, pp. 1-110 (b) Nugent, T.C. (2010) in Chiral Amine Synthesis Methods, Developments and Applications, Wiley-VCH Verlag GmbH, Weinheim, p. 520  

80 (a) Itsuno, S. (1999) Hydroboration of carbonyl groups, in Comprehensive Asymmetric Catalysis, vol. 1 (eds E.N.P. Jacobsen, A. Pfaltz, and H. Yamamoto), Springer-Verlag, Berlin, pp. 289-315  

85 (a) Nishimura, S. (2001) Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis, Wiley-Intersdence  

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