Chemical Speciation in the Solution State

Significant work has been reported utilizing solution-state H, C, and SiNMRto characterize the structure and chemistry of siloxane-based polymer systems [19]. Extensive lists of chemical shifts have been tabulated [19-22] and standard one- and two-dimensional NMR methods such as COSY, HSQC, and HMBC are routinely used to characterize soluble siloxane polymers of low to moderate molecular weight 

Solution-state methods Solid-state methods Imaging methods 

Multidimensional, multinuclear experiments for unambiguous structure determination  

Characterization of dynamics over timescales spanning greater than 10 decades  

Spedation of networks via solvent swelling (quasi-solution state) Characterization of response to stress in situ  

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