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Chemical equilibrium in non ideal solutions classical theory

1 Chemical equilibrium in non ideal solutions classical theory [Pg.88]

The correct expression of the chemical equilibrium and the corresponding mass action law in solution requires the minimization of the full free enthalpy of the solution, which includes the solvent contribution [24], We need to minimize the free energy of the solute pair formation equilibrium [Pg.88]

The excess free energy and osmotic coefficient p can be computed for the Coulomb [21] and hard sphere parts at the MSA level, we have [Pg.89]

Subject to the constraints imposed by material the balance relations [Pg.89]

They are essentially the chemical potentials and lead to the mass action law [Pg.90]




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Chemicals classical

Classical theories

Equilibrium in solutions

Equilibrium theory

Ideal solution

Ideal solution chemical equilibrium

Ideal solution theory

In non-ideal solution

Non-classical

Non-equilibrium

Non-ideal

Non-ideal solution

Non-ideality

Solutal equilibrium

Solutes equilibrium

Solution chemical equilibrium

Solution equilibrium theory

Solution ideal solutions

Solution theory

Solutions equilibrium

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