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Chemical Effects of Nuclear Activation

Chemical Effects of Nuclear Activation in Gases and Liquids I. G. Campbell Gaseous Hydroxides... [Pg.437]

Nuclear magnetic resonance (NMR) spectroscopy has been applied to elucidate metal-binding mechanisms to organic ligands mainly by two approaches by measuring the effects of metal complexation on either the relaxation times of H of water molecules solvating the metal cation or on the chemical shifts of NMR-active metal ions (e.g.. Cd, Al, and Pb) (e.g., Connors, 1987 Wilson, 1989 Macomber, 1998). Relatively few and sparse studies have been performed by NMR on metal-HS complexes. A comprehensive and updated review has been provided by Kmgery et al. (2001) on the various applications of NMR spectroscopy to the study of metal-HS interactions. [Pg.149]


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