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Charge density waves . high electronic structure

To emphasize the importance of structural studies at LT or HP, let us take the example of TTF-TCNQ. This prototype charge density wave (CDW) system undergoes at ambient pressure a succession of three structural and electronic phase transitions, from a high-temperature metallic phase down to a low-temperature insulator phase. There has been a considerable debate about the mechanism of these transitions, and many distortional modes have been proposed to account for the physical properties of this material (e.g., rigid molecule displacement as translations [73,74] or librations [75,76] or even internal deformations of the molecules [77,78]. Indeed, an experi-... [Pg.164]


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Charge density waves

Charge structural

Density electronic structures

Density waves

Electron charge density

Electron density structure

Electron wave structure

Electron-density wave

Electronic charge density

Electronic charges

High charge density

Structural density

Structural waves

Wave structure

Waves electrons

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