Chalcogens complexes

The single-bond compounds between Si, Ge, and Sn and chalcogens (S, Se, Te) are reactive and used as synthetic intermediates in the synthesis of organic compounds, organochalcogen compounds, organo-silicon, -germanium and -tin compounds, and transition metal-chalcogen complexes and clusters. 

Table 6.20. 2p i — 2po spacings and ionization energies (meV) of ChcXi chalcogen complexes in silicon [262]... 

A review of the complexes of sulfur and tellurium in 1964 was followed by an extensive survey of the heavy chalcogen complexes in a comprehensive text on the chemistry of selenium, tellurium and polonium in 1966. The subject of coordination in organoselenium and organotellurium chemistry, together with the structural chemistry of complexes of selenium and tellurium with sulfur- and selenium-containing ligands, has received recent attention in... 

Spencer, L. R, Yang, R, Scott, B. L., Batista, E. R. BonceUa, J. M. Uranimn(VI) bis(imido) chalcogenate complexes synthesis and density functional theory analysis. Inorg. Chem. 48, 2693-2700 (2009). 

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