Free radical chain processes in aliphatic

Chain processes, free radical, in aliphatic systems involving an electron transfer reaction, 23,271 Charge density-NMR chemical shift correlation in organic ions, 11,125 Chemically induced dynamic nuclear spin polarization and its applications, 10, 53 Chemiluminescence of organic compounds, 18,187... [Pg.336]

Chain processes, free radical, in aliphatic systems involving an electron transfer reaction,... [Pg.354]

Electron-transfer reaction, free radical chain processes in aliphatic systems involving an, 23, 271 Electron-transfer reactions, in organic chemistry, 18,79 Electronically excited molecules, structure of, 1, 365... [Pg.337]

Force-field methods, calculation of molecular structure and energy by, 13,1 Free radical chain processes in aliphatic systems involving an electron-transfer reaction, 23, 271 Free radicals, and their reactions at low temperature using a rotating cryostat, study of, 8. I Free radicals, identification by electron spin resonance, 1, 284... [Pg.337]

Electron-transfer reaction, free radical chain processes in aliphatic systems involving an, 23, 271... [Pg.355]

The first attempts at ROP have been mainly based on anionic and cationic processes [4,5]. In most cases, polyesters of low molecular weight were recovered and no control on the polymerization course was reported due to the occurrence of side intra- and intermolecular transesterification reactions responsible for a mixture of linear and cyclic molecules. In addition, aliphatic polyesters have been prepared by free radical, active hydrogen, zwitterionic, and coordination polymerization as summarized in Table 2. The mechanistic considerations of the above-mentioned processes are outside the scope of this work and have been extensively discussed in a recent review by some of us [2 ]. In addition, the enzyme-catalyzed ROP of (di)lactones in organic media has recently been reported however, even though this new polymerization procedure appears very promising, no real control of the polyesters chains, or rather oligomers, has been observed so far [6]. [Pg.5]

Primary aliphatic alcohols are air-oxidized to the corresponding esters in the presence of a bromine-nitric acid catalyst. Evidence supporting a mechanism, which is not a free radical chain process, is presented. [Pg.389]

Free Radical Chain Processes in Aliphatic Systems involving an Electron Transfer Process... [Pg.49]