Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Cerium sulfate secondary alcohols

Cerium (TV) ammonium nitrate (CAN)37 and a cerium (TV) impregnated resin38 are able to catalyze the selective oxidation of secondary alcohols with sodium bromate (NaBrOi). Stoichiometric cerium bromate— CelBrCb h, prepared in situ from barium bromate and cerium (III) sulfate, is also able to perform selective oxidations of secondary alcohols.39... [Pg.346]

Ammonium cerium(IV) nitrate or cerium(IV) sulfate will catalyze the selective oxidation of secondary alcohols with sodium bromate as cooxidant, in this case remote C—C double bonds interfere, but 1,2-diols are not cleaved. It has been found that sodium bromite in aqueous acetic acid will act as a selective oxidant for secondary/primary diols without the need for other catalysts (Scheme 21). ... [Pg.322]

See other pages where Cerium sulfate secondary alcohols is mentioned: [Pg.319]   
See also in sourсe #XX -- [ Pg.322 ]

See also in sourсe #XX -- [ Pg.322 ]

See also in sourсe #XX -- [ Pg.7 , Pg.322 ]

See also in sourсe #XX -- [ Pg.7 , Pg.322 ]

See also in sourсe #XX -- [ Pg.322 ]



SEARCH



Alcohols secondary alcohol

Alcohols sulfated

Cerium sulfate

Sulfate secondary

© 2024 chempedia.info