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Energy cavity formation

Large ions, for example, iodide, exhibit a very strong affinity toward the stationary phase of an anion exchanger. In these large ions, the hydration enthalpy is partly counterbalanced by the cavity formation energy. Such ions are termed polarizable anions in the following their chromatography is discussed separately. [Pg.80]

In the paper referred to, the relevance of the theoretical considerations has been tested on experimental solvation free energies of nitromethane as the solute in select solvents. The total solvation energy is a competition of the positive cavity formation energy and the negative solvation energy of dispersion and dipolar forces,... [Pg.750]

A simple but effective theory for calculating the cavity formation energy is the scaled particle theory (SPT) [6]. According to the scaled particle theory, the cavity formation energy is expressed as... [Pg.26]

XYZ = XYZq + Cavity formation energy + Solute - solvent interaction energy (7.6)... [Pg.469]

See other pages where Energy cavity formation is mentioned: [Pg.44]    [Pg.57]    [Pg.112]    [Pg.40]    [Pg.6]    [Pg.6]    [Pg.7]    [Pg.9]    [Pg.156]    [Pg.147]    [Pg.271]    [Pg.272]    [Pg.28]    [Pg.41]    [Pg.182]    [Pg.649]    [Pg.740]    [Pg.748]    [Pg.647]    [Pg.649]    [Pg.740]    [Pg.748]    [Pg.26]    [Pg.28]    [Pg.29]    [Pg.274]    [Pg.120]    [Pg.210]    [Pg.218]    [Pg.25]    [Pg.659]    [Pg.757]    [Pg.770]   
See also in sourсe #XX -- [ Pg.7 ]



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