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Cavities with aliphatic alcohol guests

Table 5 Molecular volume of guests (Vg), host cavity (Vc) and PCcavity in the inclusion compounds of CAM with aliphatic alcohols. Table 5 Molecular volume of guests (Vg), host cavity (Vc) and PCcavity in the inclusion compounds of CAM with aliphatic alcohols.
This internal cavity which is highly hydrophobic can accommodate a wide range of guest molecules, ranging from polar compounds such as alcohols, acids, amines, and small inorganic anions to apolar compounds such as aliphatic and aromatic hydrocarbons. In all cases, the guest is bound at least partially, within the cavity of the CD. The driving forces for the inclusion complexation of CD with substrates are attributed to several factors such as van der Waals forces, hydrophobic interactions, electronic effects, and steric factors. ... [Pg.783]


See other pages where Cavities with aliphatic alcohol guests is mentioned: [Pg.105]    [Pg.105]    [Pg.228]    [Pg.163]    [Pg.214]    [Pg.1180]    [Pg.55]    [Pg.1051]    [Pg.70]    [Pg.71]    [Pg.15]    [Pg.149]    [Pg.842]    [Pg.52]   
See also in sourсe #XX -- [ Pg.105 ]




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Aliphatic alcohols

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