Catalysis of Nucleophilic Substitution in Phosphate Esters

Department of Chemistry, Queen s University, Kingston, Ontario, Canada K7L 3N6 

Lash Miller Chemical Laboratories, Department of Chemistry, University of Toronto, Toronto, Canada MSS lAl 

The name of the reaction 101 Generalizations 102 Dissociative mechanisms 102 Kinetic analysis and the possibility of dissociative reactions at phosphorus 102 

Stereochemical tests for the intermediacy of metaphosphate 114 Other tests for intermediates 117 The prospects for metaphosphate 121 Addition-elimination mechanisms 122 Introduction 122 

Westheimer s guidelines for associative nucleophilic substitution at phosphorus 122 

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Mechanism and Catalysis of Nucleophilic Substitution in Phosphate Esters... 

Mechanisms and Catalysis of Nucleophilic Substitution in Phosphate Esters. Thatcher, G. R. J. Kluge, R. Adv. Phys. Chem. 1989, 25, 99-265. 

Nucleophilic substitution, in phosphate esters, mechanism and catalysis of, 25,99 Nucleophilic substitution, single electron transfer and, 26, 1 Nucleophilic vinylic substitution, 7,1... 

Partitioning of carbocations between addition of nucleophiles and deprotonation, 35, 67 Perchloro-organic chemistry structure, spectroscopy and reaction pathways, 25, 267 Permutational isomerization of pentavalent phosphorus compounds, 9, 25 Phase-transfer catalysis by quaternary ammonium salts, 15, 267 Phosphate esters, mechanism and catalysis of nucleophilic substitution in, 25, 99 Phosphorus compounds, pentavalent, turnstile rearrangement and pseudoration in permutational isomerization, 9, 25... 

Nucleophilic substitution in phosphate esters, mechanism and catalysis of, 25, 99... 

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