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Carboxylic cleavage with neighboring

Peptides (s. a. Carboxylic acid amides, subst.) cleavage with neighboring group participation 26, 28 suppl. 29... [Pg.266]

If the other major product, 13, arises by nucleophilic attack of 14 on 12, it represents, as pointed out by Laughlin (207), an unusual mode of cleavage of a carboxylate ester. A neighboring group effect may be operative. Although elevated temperature (250°) is required for reaction of dodecyl acetate with dimethyl methylphosphonate, cleavage of the carbon-oxygen bond also occurs (207). [Pg.80]

See other pages where Carboxylic cleavage with neighboring is mentioned: [Pg.335]    [Pg.335]    [Pg.281]    [Pg.396]    [Pg.222]    [Pg.209]    [Pg.576]    [Pg.33]    [Pg.266]    [Pg.66]    [Pg.144]    [Pg.1731]    [Pg.864]    [Pg.1936]    [Pg.495]    [Pg.66]    [Pg.2130]    [Pg.311]    [Pg.1040]    [Pg.287]    [Pg.6540]    [Pg.15]    [Pg.150]    [Pg.247]    [Pg.454]   


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Carboxylic cleavage

Neighbor

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