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Carboxylic Acid Derivatives Self-Assembly and Sensors

4 Carboxylic acid derivatives self-assembly and sensors [Pg.33]

PT tlisassembled by lar metal detection, disordered and not conjugated COLOR-YELLOW color tunable-yellow, orange, red [Pg.33]

Self-Assembled PT disassembling by large metal detection -very rapidly losing conjugation [Pg.33]

PT in metal-drivett self-assembled state, after detection of smalt metal, very highly conjugal COLOR-PURPLE [Pg.33]

Irregular polythiophenes carrying carboxylic acids [170] have been prepared elec-trochemically and dramatic ionochromism or ionic self-assembly was not reported. However, other reports have looked at irregular PT carboxylic add derivatives in competitive immunoassays for antigens and haptens [171]. The carboxylate function attached directly to the thiophene ring has been reported to be prepared [172] from the 2,5-dichloro-3-methylthiophene carboxylate by the Yamamoto route [8]. [Pg.34]




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