Carboranes carborane complexes

Copper and gold carborane complexes are discussed with the metalloboranes ( 6.5.3.4.). 

Tc-carborane complex reported to date. A new method for the preparation of Re- and "mTc-metallacarboranes in water under mild reaction conditions was later developed by the same investigators.673... 

In addition to the mixed Cp/carborane complexes, there has been one report on the lanthanacarboranes with the open pentadienyl ligand, R7C5 (R = H or an alkyl derivative). This is an alternate 6-7T electron donor that has led to the syntheses of number of so-called open metallocenes where the pentadienyl group replaces one or more Cp ligands. This lanthanacarborane report covered the syntheses and structural determinations of two open... 

The existence of the Mn(CO) -carborane complex was inferred 54) by the observation of rapid precipitation of NaBr from the reaction mixture , whereas CO evolution did not occur until the resulting solution was heated to reflux. 

Redistribution Equilibria of Organometallic Compounds, 6, 171 Radiochemistry of Organometallic Compounds, 11, 207 Strengths of Metal-to-Carbon Bonds, 2, 49 Structural Aspects of Organotin Chemistry, 5, 137 Structural Chemistry of Organo-Transition Metal Complexes, 3, Structures of Organolithium Compounds, 3, 365 Transition Metal-Carborane Complexes, 8, 87 Transition Metal-Isocyanide Complexes, 11, 21... 

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