Iridium, carbonylchlorobis

Iridium, carbonylchlorobis(triphenylphosphine) solid state reactions with hydrogen chloride, 1, 470 Iridium, dihalodicarbonyl-, 6, 142 Iridium, hexachloro-catalysts... [Pg.145]

Trans -Carbonylchlorobis(tricyclohexylphosphine)iridium (I), IrCl(CO)(PCy3)2. Solid PCy3 (0.2 g) and LIrCl(COT)2]2 (0.1 g) were placed under a CO atmosphere. The mixture turned blackish green, but when 10 mL toluene was added the stirred mixture became lighter and after 2 hr it precipitated a yellow solid that was collected and washed with ethanol (80%). We found carbon, 54.2 hydrogen, 8.2. C37H660ClP2Ir requires carbon, 54.4 hydrogen, 8.2. [Pg.161]

A flask containing 5.6 g (7.1 mmole) of carbonylchlorobis(triphenylphos-phine)iridium(I) suspended in 50 mL of benzene and equipped with a magnetic stirrer is attached to a vacuum line, frozen in liquid nitrogen, and evacuated. Trimethylphosphine (2.2 g, 28.4 mmole) is condensed into the flask, which is then closed off from the line and allowed to warm to room temperature with stirring. The resulting suspension is filtered (in air) and the solid is washed with benzene to remove traces of yellow color and then dried in vacuum. The yield of [Ir(CO)-(P(CH3)3)4]C1 is 4.0 g (98%). [Pg.64]

ClHgNjOgPt, Platinum(II), diamineaqua-chloro-, trans-, nitrate, 22 125 CIIrOPCi7H22, Iridium(I), carbonylchlorobis-(dimethylphenylphosphine)-, trans-, 21 97... [Pg.250]

CUrOP2C3,H3g, Iridium, carbonylchlorobis-(triphenylphosphine)-, trans-, 28 92 ClIrPjC54H45, Iridium(l), chlorotris(tri-phenylphosphine)-, 26 201... [Pg.354]

IrBF4P2C44H42, Iridium(l +X ( ( -l,5-cyclooctadiene)bis(tripbenylpbospbine)-, tetrafluoroborate(l—X 26 122, 28 56 IrClOP2C37H30, Iridium, carbonylchlorobis-(tripbenylpbospbineK trans-, 28 92 IrClP3C54H45, lridium(lX chlorotris(tri-phenylpbospbine)-, 26 201 —, Iridium(IIIX cbloro[2-dipbenyl-... [Pg.412]

C,7H,4, l,4-Pentadien-3-one, 1,5-diphenyl-, palladium complex, 28 110 OClIrP2C37H]o, Iridium, carbonylchlorobis-(triphenylphosphineK trans-, 28 92 OCILuCijHjg, Lutetium, chloro(i -l,3,5,7-cyclooctatetraene)(tetrahydrofuran)-, 27 152... [Pg.426]

C29H29C0F6N5P C2H3N, [(7-(cis-p-Vinylide)-7,16-dihydro-6,18,15,17-tetramethyldibenzo[b,i]-[l,4,8,11]-tetraazacyclotetradecinato)pyr-idinecobalt(III)] hexafluorophosphate - acetonitrile, 45B, 883 C2 9H3iPaPt, [Bis(diphenylphosphino)methanide][dimethylphosphonium bis(methylide)]platinum(II), 46B, 1274 C2 9H3 5BCl3Fi,I rP2 f Carbonylchlorobis(trimethyIphosphine) (1, 2,3-tri-phenylpropenylium-1,3-diyl)iridium(1+) tetrafluoroborate(1-) - di-chloromethane, 38B, 752... [Pg.403]

C20H2 7ClF6lrOP3, (T -Allyl)carbonylchlorobis(dimethylphenylphos-phine) iridium(III) hexafluorophosphate, 43B, 1045 C20H30C0N2O8, Bis(ethylfumarate)bis(acetonitrile)cobalt(0), 43B,... [Pg.421]

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