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Carbon-oxygen bonds intramolecular additions

C-M bond addition, for C-C bond formation, 10, 403-491 iridium additions, 10, 456 nickel additions, 10, 463 niobium additions, 10, 427 osmium additions, 10, 445 palladium additions, 10, 468 rhodium additions, 10, 455 ruthenium additions, 10, 444 Sc and Y additions, 10, 405 tantalum additions, 10, 429 titanium additions, 10, 421 vanadium additions, 10, 426 zirconium additions, 10, 424 Carbon-oxygen bond formation via alkyne hydration, 10, 678 for aryl and alkenyl ethers, 10, 650 via cobalt-mediated propargylic etherification, 10, 665 Cu-mediated, with borons, 9, 219 cycloetherification, 10, 673 etherification, 10, 669, 10, 685 via hydro- and alkylative alkoxylation, 10, 683 via inter- andd intramolecular hydroalkoxylation, 10, 672 via metal vinylidenes, 10, 676 via SnI and S Z processes, 10, 684 via transition metal rc-arene complexes, 10, 685 via transition metal-mediated etherification, overview,... [Pg.76]

Carretero and co-workers reported that the a-sulfonyl radicals resulting from such radical additions to y-oxygenated-a,P-unsaturated sulfones are useful intermediates for the generation of a second carbon-carbon bond via intramolecular addition to a suitably located carbon-carbon double bond.46,47 The highly functionalized acyclic y-hydroxy vinyl sulfone 68 underwent a novel cascade process, based on two sequential radical cyclizations, affording the bicyclic compounds 69 and 70 in good yield (Scheme 18). [Pg.168]

Figure 2 In the peptide Phe-Gly-Cys-Gly (formed by Phenylalanine, Glycine, Cysteine and Glycine amino adds linked by peptidic bonds), the sulphur atom is very close to the phenyl ring. An Intramolecular addition ofthe CysS radical on the aromatic ring of Phe (marked with an arrow) leads easily to the alkylthio-substituted cyclohexadie-nyl radicals. A tom colors Cyan carbon blue nitrogen red oxygen yellow sulphur. H atoms are not shown. Figure 2 In the peptide Phe-Gly-Cys-Gly (formed by Phenylalanine, Glycine, Cysteine and Glycine amino adds linked by peptidic bonds), the sulphur atom is very close to the phenyl ring. An Intramolecular addition ofthe CysS radical on the aromatic ring of Phe (marked with an arrow) leads easily to the alkylthio-substituted cyclohexadie-nyl radicals. A tom colors Cyan carbon blue nitrogen red oxygen yellow sulphur. H atoms are not shown.

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Addition oxygen

Additives carbon

Carbon addition

Carbon intramolecular

Carbon oxygenated

Carbon oxygenation

Carbon-oxygen bond

Carbon-oxygen bonds addition

Intramolecular addition

Intramolecular bonding

Intramolecular bonds

Oxygen intramolecular

Oxygenate additive

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