Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Nitrogen-carbon bonds lithium metal

In reaction (ii), 1-hexene reacts with diethyl azodicarboxylateby an ene reaction to give directly the new carbon-nitrogen bond at the terminal carbon atom. The lithium metal in liquid ammonia cleaves the nitrogen-nitrogen bond to give the aUylic amine product. For a review on allylic amination, see M. Johannsen and K. A. Jprgensen, Chem. Rev., 98 (1998), 1689. Intermediate ... [Pg.482]

See other pages where Nitrogen-carbon bonds lithium metal is mentioned: [Pg.217] [Pg.293] [Pg.27] [Pg.66] [Pg.113] [Pg.73] [Pg.719] [Pg.719] [Pg.395] [Pg.395] [Pg.139] [Pg.476] [Pg.205] [Pg.57] [Pg.159] [Pg.307] [Pg.155] [Pg.741] [Pg.504] [Pg.37] [Pg.262] [Pg.382] [Pg.476] [Pg.876] [Pg.137] [Pg.15] [Pg.21] [Pg.182] [Pg.218] [Pg.13] [Pg.166] [Pg.167] [Pg.81] [Pg.98] [Pg.251] [Pg.1004] [Pg.31] [Pg.241] [Pg.369] [Pg.60] [Pg.166] [Pg.167]