Carbon monoxide reactivity

Carbon monoxide, reactivity of carbonium ions towards, 10,29... 

Although this classic picture evolved from "soft, mononuclear transition metal complexes suffices to explain a great deal of carbon monoxide chemistry, it is not clear that it is complete or accurate for understanding processes whereby CO is reduced, deoxygenated, and/or polymerized to form methane, long-chain hydrocarbons, alcohols, and other oxocarbons, especially in cases where heterogeneous catalysts or "hard" metals are involved (6, 7, ,9,J 0). This deficiency of information has led to the search for new modes of carbon monoxide reactivity and to attempts to understand carbon monoxide chemistry in nontraditional environments ... 

Carbon atoms, energetic, reactions with organic compounds, 3, 201 Carbon monoxide, reactivity of carbonium ions towards, 10, 29... 

For a detailed discussion, compare Cornils, B, (1980) in New Syntheses with Carbon Monoxide, Reactivity and Structure, Concepts in Organic Chemistry, vol. 11 (ed, J, Falbe), Springer-Verlag, Berlin, pp, 38 —45. 

Jaron S, Blackburn NJ. 1999. Does superoxide channel between the copper centers in peptidylglycine monooxygenase a new mechanism based on carbon monoxide reactivity. Biochemistry 38 15086-15096. 

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