Carbon Monoxide Free Aminocarbonylation of lodoalkenes

Many efforts have been devoted to the development of iimovative ways for transferring a carbonyl group by using substitutes for carbon monoxide [52]. Thus, the palladium-catalyzed reaction of iodoalkene 41 with DMF in the presence of POCI3 afforded the corresponding amide 42. Very likely, the reaction proceeded via the 

Carbamoylsilane also led to the CO-free aminocarbonylation of alkenyl halides through catalysis by palladium complexes [54]. 

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