Carbohydrate polymers, glass transition

Chung, H.-J., Lee, E.-J., and Lim, S.-T. (2002). Comparison in glass transition and enthalpy relaxation between native and gelatinized rice starches. Carbohydr. Polym. 48, 287-298. 

Chung, H. -J., Woo, K. -S., Lim, S. -T. (2004). Glass transition and enthalpy relaxation of eross-linked corn starches. Carbohydr. Polym., 55, 9-15. 

The glass transition of amylopectin measured by DSC, DMTA and NMR. Carbohydr. Polym., 18, 77-88. 

Lazaridou, A., and Biliaderis, C.G. (2002). Thermophysical properties of chitosan, chitosan-starch and chitosan-pullulan films near the glass transition. Carbohydrate Polymers. 48,... 

Slade, L. and Levine, H. Non-equilibrium melting of native granular starch Part I. Temperature location of the glass transition associated with gelatiniza-tion of A-t)q)e starches, Carbohydr. Polym., 8, 183, 1988. 

Thiewes, H.J. and Steeneken, P.A.M. The glass transition and the sub-Tg endotherm of amorphous and native potato starch at low moisture content, Carbohydr. Polym., 32,123,1997. 

According to the glass transition theory, lipids are dispersed in the free volume of the food matrix composed of carbohydrates and protein polymers. In the rubbery state, the lipids react readily with oxygen and become oxidized. In the glassy state, however, the lipids are stable to oxidation because they are encapsulated and there is no free volume. The glass transition temperature, which determines when the food matrix changes from one state to the other, increases with a decrease in moisture and water activity. In many foods the... 

ForseU EM., Mikkila J.M., Moates G.K., Parker R. Phase and glass transition behaviour of concentrated barley starch-glycerol-water mixtures, a model for thermoplastic starch, Carbohydr. Polym. 34(1997)275. 

Glass transition temperature °c 163-172 Martinez-Camacho, A P Cortez-Rocha, M O Ezquerra-Brauer, J M Graciano-Vercdugo, AZ Rocdriguez-Felix, F Castillo-Ortega, M M Yepiz-Gomez, M S Plascencia-J M, Carbohydrate Polym., 82, 305-15,2010. 

Glass transition temperature °c -4.2 to -7.0 21-43 Lopez-Velazquez, D Hemandez-Sosa, A R Perez, E, Carbohydrate Polym., 125, 224-31,2015. 

Biliaderis, C. G., Lazaridou, A. Arvanitoyannis, I. (1999). Glass transition and physical properties of polyol-plasticized pulluan-starch blend at low moisture. Carbohydrate Polymers, 40(1), 29-47. 

Bizot, H., Le Bail, P., Leroux, B., Davy, J., Roger, P. and Buleon, A. (1997) Calorimetric evaluation of the glass transition in hydrated, linear and branched polyanhydroglucose compounds. Carbohydrate Polymers, 32,... 

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