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Carbocyclic polyoxin

Miller and coworker report a total syndiesis of carbocyclic polyoxin C from cis-(N- en-butylcarbamoyl cyclopent-2-en-Tol, as shovm in Scheme 5.11. This syndiesis feanires a... [Pg.144]

SCHEME 6.15 Aggarwal s S3mthetic strategy of carbocyclic polyoxin C (43). [Pg.163]

The opening of the cyclopentene moiety involved the ozonolysis of the double bond and this has been used by Hon for the synthesis of alkenyl butyrolactones. This cyclopentene cycle could also be used for the palladium-catalyzed nucleophilic substitution of the C-4 of the fused lactones. By this strategy, Aggarwal described an access to carbocyclic uracil polyoxin C and the nikkomycins analogues." " ... [Pg.41]

See other pages where Carbocyclic polyoxin is mentioned: [Pg.163]    [Pg.163]    [Pg.164]    [Pg.164]    [Pg.163]    [Pg.163]    [Pg.164]    [Pg.164]    [Pg.400]    [Pg.400]    [Pg.580]   
See also in sourсe #XX -- [ Pg.163 ]



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